LiNbO3
LiNbO3 is widely used as electro-optic modulator and Q-switch for Nd:YAG, Nd:YLF and Ti:Sapphire lasers as well as modulator for fiber optics, etc. The transverse modulation is mostly employed for LiNbO3 crystal.
If the light propagates in z-axis and electric field applies to x-axis, the refractive retardation will be G = p Lnr22V/ l d. The electro-optic coefficients of LiNbO3 are:
r 33 = 32 pm/V, r 31 = 10 pm/V, r 22 = 6.8 pm/V at low frequency
r 33 = 31 pm/V, r 31 = 8.6 pm/V, r 22 = 3.4 pm/V at high electric frequency.
MgO:LiNbO3 and ZnO: LiNbO3 crystals have similar electro-optic properties to LiNbO3 but with higher damage threshold.
The refractive index of an optical medium is altered by the presence of sound, this is called acousto-optic effect which can be used in many devices include optical modulators, switches, deflectors, filters, frequency shifters and spectrum analyzers. JH Optek provide several kinds of acousto-optic crystals: LiNbO3 SAW wafers, LiTaO 3 SAW wafers. TeO 2 and PbMnO 4 crystals.
KTP Crystal
KTP has promising E-O and dielectric properties comparable to those of LiNbO3, which makes it extremely useful to various E-O devices. The following table gives the comparison of KTP and those commonly used E-O modulator materials:
Material | Phase | Amplitude | ||||||
e | 5 | r pm/V | k 10 -6 /°C | n 7 r 2 / e | r pm/V | k 10 -6 /°C | n 7 r 2 / e | |
KTP | 15.4 | 1.80 | 35.0 | 31 | 6130 | 27.0 | 11.7 | 3650 |
LiNbO3 | 27.9 | 2.20 | 31.0 | 82 | 7410 | 20.1 | 42 | 3500 |
KD*P | 48.0 | 1.47 | 26.4 | 9 | 178 | 24.0 | 8 | 178 |
LiIO3 | 5.9 | 1.47 | 6.4 | 24 | 335 | 1.2 | 15 | 124 |
When these properties are combined with high damage threshold, low optical loss at high average power, wide optical bandwidth, thermal and mechanical stability, KTP crystals are expected to replace LiNbO3 crystals as E-O modulators, especially for mode-locking diode laser pumped Nd:YAG and Nd:YLF lasers as well as Ti:Sapphire and Cr:LiSrAlF 6 lasers.
LiTaO3
LiTaO3 crystal is also widely used E-O crystal, due to its optical, NLO and E-O properties similar to those of LiNbO3 crystal, but with higher damage threshold (> 500 MW/cm 2 for ns pulsed).
Properties
Transparent Range: 0.4 - 5.0 µm;
E-O Coefficient: r 33 =30.4;
Refractive Indices: n o =2.176, n e =2.180 @ 633 nm.
Capabilities:
Diameter: f 40mm ~ f 102mm
Length: 50mm ~ 150mm
Orientation: X, Z, 36°Y, 42°Y, 128°Y
Polish: 0.016 m m
Wafers:
· Diameter: f 40mm ~ f 102mm
· Length: 0.2~1.2mm
· Orientation: X, Z, 36°Y, 42°Y, 128°Y
· Flatness:
<10mm for f 40 ~ 65mm
<15mm for f 65 ~ 102mm
· Bow:
<20mm for f 40~ 65 mm
<40mm for f 65 ~102mm
Slices:
· Size: 100x45x1.5mm ~ 120x40x2mm
Parameter of LN and LT
Part Name: ------------LiNbo3 ------------LiTaO3
Crystal Class: -------Trigonal -------------Trigonal
Point Group:---------------3m------------------- 3m
Space Group: --------------R3c ----------------R3c
Lattice Point: ----a:0.5148 c:1.3863 --------a:0.5154c:1.3784
Melting Point: -----------1250 ---------------------1650
Density: -------------------4.64 ---------------------7.46
Curie Temp: ---------------~1160 --------------------~607M
Hardness:---------------------5-------------------------- 5.5
Dielectric Coefficient; -e 11/E0:85 e 33/E0:29.5--------- e 11/E0:51.7 e33/E0:44.5
Elastic Stiffness ----------CE11:2.04 ---------------CE11:2.33
Coefficient:(x10 -11 C/m2) -------CE11:2.46 -------CE11:2.77
Piezoelectric Stresses --------d22:2.04 -------------d22:2.4
Coefficient (x10 -11 C/N) --------d22:19.22 -----------------d22:0.8
BBO Crystal
BBO is an outstanding crystal for many applications in nonlinear optics and electro-optics. BBO is a colorless trigonal uniaxial crystal with low hygroscopic susceptibility. Its transparency range is from 0.19m to 3.5m.
BBO is an efficient nonlinear crystal for second, third, fourth and fifth harmonic generators of Nd: Laser, dye lasers and ultrafast Ti:Sapphire lasers. It has also excellent performance in optical parametric amplifier, oscillators, etc.
Specifications
· 0°, =0°, For Type I phase matching application. · 0°, =30°, For Type II phase matching application. · Brewster cut, 0°, =0°, or 30°, no coating on S1&S2. · Z-cut, gold coated on X-faces, for Q-switch application. Coating · Protective coating is required to prevent polished surfaces from fogging. · Anti-reflective coating should be considered if low reflectivity is required. |
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Ultra thin BBO Plate
The minimum thickness of BBO we can polish is 0.005mm, the ultra thin BBO is used for frequency conversion of ultra fast laser with femtosecond pulse width. For frequency conversion of ultrafast lasers such as Ti:sapphire and Dye laser with femtosecond pulse width.
The main concern is fs pulse broadening induced by group velocity mismatching(GVM) or group velocity dispersion. The suggested thickness of BBO crystals is less than pulse width divides.
Phase matching angle
The phase matching angle is depended on different applications of frequency conversion. The familiar phase matching angles are listed below.
SHG@1064nm Type I | =22.8°, =0° |
SHG@780nm Type I | =29.9°, =0° |
SHG@532nm Type I | =47.6°, =0° |
SHG@410nm Type I | =86.9°, =0° |
SFG@1064+532nm Type I | =31.3°, =0° |
SFG@1064+532nm Type II | =38.5°, =30° |
OPO 532nm pump Type I | =21.0°, =0°(tunable range 680-2600nm) |
OPO 355nm pump Type I | =30.0°, =0°(tunable range 410-2600nm) |
OPO 266nm pump Type II | =39.0°, =30°(tunable range 295-2600nm) |
If you are not sure to calculate the phase matching angles, please contact us for assistance.
BBO Optical properties
Refractive indices | ne=1.5425, no=1.6551@1064nm |
ne=1.5555, no=1.6749@532nm | |
ne=1.6146, no=1.7571@266nm | |
Therm-optic coefficients | dno/dT=-9.3x10-6/℃ |
dne/dT=-16.6x10-6/℃ | |
NLO coefficients | d11=5.8xd36(KDP) |
d31=0.05xd11 | |
d22<0.05xd11 | |
Half wave voltage | 48KV@1064nm |
Damage threshold | 5GW/cm2, 10ns, 1064nm |
Sellmeier equations | no2( )=2.7359+0.01878/( 2-0.01822)-0.01354 2 |
ne2( )=2.3757+0.01224/( 2-0.01667)-0.01516 2 |
BBO Physical properties:;
Crystal structure | Trigonal, space group R3c |
Cell parameters | A=B=12.532A, C=12.717A, Z=6 |
Melting point | 1095℃ |
Transition temperature | 925℃ |
Mohs hardness | 4.5 |
Optical coefficient | <0.1%/cm @1064nm |
Density | 3.85g/cm3 |
Hygroscopic susceptibility | Low |
Resistivity | >1011 ohm-cm |
Thermal expansion coefficients | ⊥C, 4x10-6/K;∥C, 36x10-6/k |
Thermal conductivity | ⊥C, 1.2w/m/k;∥C, 1.6w/m/k |
We can provide as large as 10x10x25mm BBO for high power application.